Location: Svobody 8, 771 46 Olomouc
Phone: (+420) 58 563 4427
Fax: (+420) 58 563 4425
Oblast výzkumu:
Colloid silver (preparation, modification, study of stability, biological activity, and electric and optical properties)
Transmission electron microscopy
Kvalifikace:
Mgr.: Education of physical training and chemistry, Palacký University
Ph.D.: Physical chemistry, Palacký University
Ukázat publikace2011
P. Praus, O. Kozak, K. Koci, A. Panacek, and R. Dvorsky, „CdS nanoparticles deposited on montmorillonite: Preparation,
characterization and application for photoreduction of carbon dioxide,“ JOURNAL OF COLLOID AND INTERFACE SCIENCE, vol. 360, iss. 2, pp. 574-579, 2011.
[Bibtex]
@article ISI:000292066100032,
Author = Praus, Petr and Kozak, Ondrej and Koci, Kamila and Panacek, Ales and
Dvorsky, Richard,
Title = CdS nanoparticles deposited on montmorillonite: Preparation,
characterization and application for photoreduction of carbon dioxide,
Journal = JOURNAL OF COLLOID AND INTERFACE SCIENCE,
Year = 2011,
Volume = 360,
Number = 2,
Pages = 574-579,
Month = AUG 15,
Abstract = CdS nanoparticles were precipitated by the reaction of cadmium acetate
with sodium sulphide in the presence of cetyltrimethylammonium (CTA) and
deposited on montmorillonite (MMT). The resulting CdS-MMT nanocomposite
contained 6 wt.\% of CdS and 30 wt.\% of CIA. Band-gap energy of CdS was
estimated at 2.63 +/- 0.09 eV using the Tauc plot. The size of CdS
nanoparticles was calculated from the band-gap energy at 5 nm and from
the micrographs of transmission electron microscopy (TEM) at 5 nm.
Selected area electron diffraction (SAED) recognized the cubic structure
of CdS (Hawleite). The dynamic light scattering (DLS) method confirmed
that CdS nanoparticles were anchored on the surface of MMT particles.
CTA was found to be intercalated into MMT and adsorbed on its external
surface. CdS-MMT was used for the photoreduction of carbon dioxide
dissolved in NaOH solutions. The yields of originating gas products can
be arranged in the order: H-2 >> CH4 > CO. Amounts of these products
were 48 folds higher then those obtained with TiO2 Evonic P25. Hydrogen
reduced CO2 to CO and CH4. (C) 2011 Elsevier Inc. All rights reserved.,
DOI = 10.1016/j.jcis.2011.05.004,
ISSN = 0021-9797,
Unique-ID = ISI:000292066100032,
R. Prucek, J. Tucek, M. Kilianova, A. Panacek, L. Kvitek, J. Filip, M. Kolar, K. Tomankova, and R. Zboril, „The targeted antibacterial and antifungal properties of magnetic
nanocomposite of iron oxide and silver nanoparticles,“ BIOMATERIALS, vol. 32, iss. 21, pp. 4704-4713, 2011.
[Bibtex]
@article ISI:000291571400003,
Author = Prucek, Robert and Tucek, Jiri and Kilianova, Martina and Panacek, Ales
and Kvitek, Libor and Filip, Jan and Kolar, Milan and Tomankova,
Katerina and Zboril, Radek,
Title = The targeted antibacterial and antifungal properties of magnetic
nanocomposite of iron oxide and silver nanoparticles,
Journal = BIOMATERIALS,
Year = 2011,
Volume = 32,
Number = 21,
Pages = 4704-4713,
Month = JUL,
Abstract = Two types of magnetic binary nanocomposites, Ag@Fe(3)O(4) and
gamma-Fe(2)O(3)@Ag, were synthesized and characterized and their
antibacterial activities were tested. As a magnetic component, Fe(3)O(4)
(magnetite) nanoparticles with an average size of about 70 nm and
monodisperse gamma-Fe(2)O(3) (maghemite) nanoparticles with an average
size of 5 nm were used. Nanocomposites were prepared via in situ
chemical reduction of silver ions by maltose in the presence of
particular magnetic phase and molecules of polyacrylate serving as a
spacer among iron oxide and silver nanoparticles. In the case of the
Ag@Fe(3)O(4) nanocomposite, silver nanoparticles, caught at the surfaces
of Fe(3)O(4) nanocrystals, were around 5 nm in a size. On the contrary,
in the case of the gamma-Fe(2)O(3)@Ag nanocomposite, ultrafine
gamma-Fe(2)O(3) nanoparticles surrounded silver nanoparticles ranging in
a size between 20 and 40 nm. In addition, the molecules of polyacrylate
in this nanocomposite type suppress considerably interparticle magnetic
interactions as proved by magnetization measurements. Both synthesized
nanocomposites exhibited very significant antibacterial and antifungal
activities against ten tested bacterial strains (minimum inhibition
concentrations (MIC) from 15.6 mg/L to 125 mg/L) and four candida
species (MIC from 1.9 mg/L to 31.3 mg/L). Moreover, acute nanocomposite
cytotoxicity against mice embryonal fibroblasts was observed at
concentrations of higher than 430 mg/L (Ag@Fe(3)O(4)) and 292 mg/L
(gamma-Fe(2)O(3)@Ag). With respect to the non-cytotoxic nature of the
polyacrylate linker, both kinds of silver nanocomposites are well
applicable for a targeted magnetic delivery of silver nanoparticles in
medicinal and disinfection applications. (C) 2011 Elsevier Ltd. All
rights reserved.,
DOI = 10.1016/j.biomaterials.2011.03.039,
ISSN = 0142-9612,
Unique-ID = ISI:000291571400003,
A. Panacek, R. Prucek, D. Safarova, M. Dittrich, J. Richtrova, K. Benickova, R. Zboril, and L. Kvitek, „Acute and Chronic Toxicity Effects of Silver Nanoparticles (NPs) on
Drosophila melanogaster,“ ENVIRONMENTAL SCIENCE & TECHNOLOGY, vol. 45, iss. 11, pp. 4974-4979, 2011.
[Bibtex]
@article ISI:000291128700045,
Author = Panacek, Ales and Prucek, Robert and Safarova, Dana and Dittrich, Milan
and Richtrova, Jana and Benickova, Katerina and Zboril, Radek and
Kvitek, Libor,
Title = Acute and Chronic Toxicity Effects of Silver Nanoparticles (NPs) on
Drosophila melanogaster,
Journal = ENVIRONMENTAL SCIENCE \& TECHNOLOGY,
Year = 2011,
Volume = 45,
Number = 11,
Pages = 4974-4979,
Month = JUN 1,
Abstract = The use of nanoscaled materials is rapidly increasing, however, their
possible ecotoxicological effects are still not precisely known. This
work constitutes the first complex study focused on in vivo evaluation
of the acute and chronic toxic effects and toxic limits of silver
nanoparticles (NPs) on the eukaryotic organism Drosophila melanogaster.
For the purpose of this study, silver NPs were prepared in the form of
solid dispersion using microencapsulation method, where mannitol was
used as an encapsulation agent. This newly prepared solid dispersion
with a high concentration of silver NPs was exploited to prepare the
standard Drosophila culture medium at a silver concentration range from
10 mg . L(-1) to 100 mg . L(-1) of Ag in the case of the acute toxicity
testing and at a concentration equal to S mg . L in the case of the
chronic toxicity testing. The acute toxic effect of silver NPs on
Drosophila melanogaster was observed for the silver concentration equal
to 20 mg . L(-1). At this silver concentration, 50\% of the tested flies
were unable to leave the pupae, and they did not finish their
developmental cycle. Chronic toxicity of silver NPs was assessed by a
long-term exposure of overall eight filial generations of Drosophila
melanogaster to silver NPs. The long-term exposure to silver NPs
influenced the fertility of Drosophila during the first three filial
generations, nevertheless the fecundity of flies in subsequent
generations consequently increased up to the level of the flies from the
control sample due to the adaptability of flies to the silver NPs
exposure.,
DOI = 10.1021/es104216b,
ISSN = 0013-936X,
Unique-ID = ISI:000291128700045,
R. Prucek, A. Panacek, J. Soukupova, R. Novotny, and L. Kvitek, „Reproducible synthesis of silver colloidal particles tailored for
application in near-infrared surface-enhanced Raman spectroscopy,“ JOURNAL OF MATERIALS CHEMISTRY, vol. 21, iss. 17, pp. 6416-6420, 2011.
[Bibtex]
@article ISI:000289524300045,
Author = Prucek, Robert and Panacek, Ales and Soukupova, Jana and Novotny, Radko
and Kvitek, Libor,
Title = Reproducible synthesis of silver colloidal particles tailored for
application in near-infrared surface-enhanced Raman spectroscopy,
Journal = JOURNAL OF MATERIALS CHEMISTRY,
Year = 2011,
Volume = 21,
Number = 17,
Pages = 6416-6420,
Abstract = Reproducible synthesis of silver colloidal particles, with diameters of
hundreds of nanometres, represents an experimentally rather difficult
task although they have revealed a great application potential in e. g.
SERS. The newly developed method, based on the reduction of the complex
anion [Ag(SO(3))(2)](3-), offers an approach enabling to manage the
preparation of silver particles with adjustable average diameters in the
interval from 200 nm up to 700 nm due to the choice of the reducing
agent and the sulfite concentration. These particles proved their
efficiency as substrates for surface enhanced Raman spectroscopy with
the excitation in the near infrared region (lambda = 1064 nm) and
therefore this newly developed method confirmed the expected application
potential.,
DOI = 10.1039/c0jm03870a,
ISSN = 0959-9428,
Unique-ID = ISI:000289524300045,
R. Prucek, A. Panacek, A. Fargasova, V. Ranc, V. Masek, L. Kvitek, and R. Zboril, „Re-crystallization of silver nanoparticles in a highly concentrated NaCl
environment-a new substrate for surface enhanced IR-visible Raman
spectroscopy,“ CRYSTENGCOMM, vol. 13, iss. 7, pp. 2242-2248, 2011.
[Bibtex]
@article ISI:000288562200014,
Author = Prucek, Robert and Panacek, Ales and Fargasova, Ariana and Ranc, Vaclav
and Masek, Vlastimil and Kvitek, Libor and Zboril, Radek,
Title = Re-crystallization of silver nanoparticles in a highly concentrated NaCl
environment-a new substrate for surface enhanced IR-visible Raman
spectroscopy,
Journal = CRYSTENGCOMM,
Year = 2011,
Volume = 13,
Number = 7,
Pages = 2242-2248,
Abstract = The common approach of silver nanoparticles activation for surface
enhanced Raman spectroscopy often exploits an addition of chloride ions,
generally at low concentrations of about 0.1-10 mM in the final
dispersion. For the first time, we report the applicability of a highly
concentrated NaCl solution (final concentration of 400 mM) for the SERS
activation of silver nanoparticles (similar to 30 nm). Microscopic,
optical and particle size distribution measurements reveal the rapid and
reproducible re-crystallization of the primary silver nanoparticles to
one-order larger crystallites (similar to 400 nm) already after 15 min
after NaCl addition. The crystal growth mechanism is discussed with
respect to the proved essential role of oxygen in the reaction system.
The specific action of chloride ions is demonstrated through a
comparison with NaBr and NaI solutions of the identical concentrations,
which do not induce the analogous crystallization process. The
recrystallized silver particles are efficient in an enhancement of the
Raman signal not only for visible (488 nm) but also for near infrared
laser excitation (1064 nm) as illustrated with the representative
spectra of adenine.,
DOI = 10.1039/c0ce00776e,
ISSN = 1466-8033,
Unique-ID = ISI:000288562200014,
2010
J. Soukupova, L. Kvitek, M. Kratochvilova, A. Panacek, R. Prucek, and R. Zboril, „Silver Voyage from Macro- to Nanoworld,“ JOURNAL OF CHEMICAL EDUCATION, vol. 87, iss. 10, pp. 1094-1097, 2010.
[Bibtex]
@article ISI:000281834400024,
Author = Soukupova, Jana and Kvitek, Libor and Kratochvilova, Martina and
Panacek, Ales and Prucek, Robert and Zboril, Radek,
Title = Silver Voyage from Macro- to Nanoworld,
Journal = JOURNAL OF CHEMICAL EDUCATION,
Year = 2010,
Volume = 87,
Number = 10,
Pages = 1094-1097,
Month = OCT,
DOI = 10.1021/ed1003405,
ISSN = 0021-9584,
Unique-ID = ISI:000281834400024,
P. Dallas, J. Tucek, D. Jancik, M. Kolar, A. Panacek, and R. Zboril, „Magnetically Controllable Silver Nanocomposite with Multifunctional
Phosphotriazine Matrix and High Antimicrobial Activity,“ ADVANCED FUNCTIONAL MATERIALS, vol. 20, iss. 14, pp. 2347-2354, 2010.
[Bibtex]
@article ISI:000280427000019,
Author = Dallas, Panagiotis and Tucek, Jiri and Jancik, Dalibor and Kolar, Milan
and Panacek, Ales and Zboril, Radek,
Title = Magnetically Controllable Silver Nanocomposite with Multifunctional
Phosphotriazine Matrix and High Antimicrobial Activity,
Journal = ADVANCED FUNCTIONAL MATERIALS,
Year = 2010,
Volume = 20,
Number = 14,
Pages = 2347-2354,
Month = JUL 23,
Abstract = A recently developed multi-functional phosphotriazine-based polymer is
used as a matrix for embedding gamma-Fe(2)O(3) nanoparticles as well as
a suitable chemical template for surface modification with silver
nanoparticles. For the; primary magnetic modification, maghemite
nanoparticles are surface modified with oleic acid in order to render
them organophilic and to prevent the aggregation of the nanoparticles.
This aggregation could occur as the polymer synthesis, based on reaction
of phosphonitrilic chlorine and 1,4phenylenediamine, takes place in
toluene. The surface active amine units of the polymer structure enable
the reduction of silver cations to silver nanoparticles, which are well
attached and finely dispersed on its surface. The developed
nanocomposite represents one of the few magnetically controllable
antibacterial agents based on silver nanoparticles. Magnetic
measurements reveal the completely suppressed interactions among
maghemite nanoparticles because of their perfect surface coating with an
organic surfactant and fine dispersion inside the polymer matrix. This
magnetic nanocomposite exhibits a high antibacterial and antifungal
activity as proven by tests with nine bacterial strains and four candida
(yeast genus) species. For the majority of the tested species, the
minimum-inhibition concentrations are below 100 mg L(-1), which is
comparable to their equivalent minimum-inhibition concentrations in
colloidal silver systems.,
DOI = 10.1002/adfm.200902370,
ISSN = 1616-301X,
Unique-ID = ISI:000280427000019,
P. Dallas, R. Zboril, A. B. Bourlinos, D. Jancik, D. Niarchos, A. Panacek, and D. Petridis, „Cornet-Like Phosphotriazine/Diamine Polymers as Reductant and Matrix for
the Synthesis of Silver Nanocomposites with Antimicrobial Activity,“ MACROMOLECULAR MATERIALS AND ENGINEERING, vol. 295, iss. 2, pp. 108-114, 2010.
[Bibtex]
@article ISI:000275287400003,
Author = Dallas, Panagiotis and Zboril, Radek and Bourlinos, Athanasios B. and
Jancik, Dalibor and Niarchos, Dimitrios and Panacek, Ales and Petridis,
Dimitrios,
Title = Cornet-Like Phosphotriazine/Diamine Polymers as Reductant and Matrix for
the Synthesis of Silver Nanocomposites with Antimicrobial Activity,
Journal = MACROMOLECULAR MATERIALS AND ENGINEERING,
Year = 2010,
Volume = 295,
Number = 2,
Pages = 108-114,
Month = FEB 12,
Abstract = The synthesis of silver nanoparticles attached on the surface of a
hollow cornet-like polymer matrix which served as a reductant and host
matrix is described. This hybrid organic/inorganic macromolecular matrix
is exhibiting anion-exchange properties, porous structure and hollow
morphologies, and absorptions in the visible light region. Due to the
anion-exchange property and the 3D orientation of the macromolecular
chains the material is defining a new functional organic/inorganic
hybrid. For the synthesis of nanoparticles, no other reducing agents
were used and silver nanoparticles with a mean diameter of less than 20
nm were attached on the surface of the polymer, thus inheriting the
composite with high antibacterial activity tested in bacterial strains
and yeasts.,
DOI = 10.1002/mame.200900258,
ISSN = 1438-7492,
Unique-ID = ISI:000275287400003,
2009
A. Panacek, M. Kolar, R. Vecerova, R. Prucek, J. Soukupova, V. Krystof, P. Hamal, R. Zboril, and L. Kvitek, „Antifungal activity of silver nanoparticles against Candida spp.,“ BIOMATERIALS, vol. 30, iss. 31, pp. 6333-6340, 2009.
[Bibtex]
@article ISI:000270767300020,
Author = Panacek, Ales and Kolar, Milan and Vecerova, Renata and Prucek, Robert
and Soukupova, Jana and Krystof, Vladimir and Hamal, Petr and Zboril,
Radek and Kvitek, Libor,
Title = Antifungal activity of silver nanoparticles against Candida spp.,
Journal = BIOMATERIALS,
Year = 2009,
Volume = 30,
Number = 31,
Pages = 6333-6340,
Month = NOV,
Abstract = The antifungal activity of the silver nanoparticles (NPs) prepared by
the modified Tollens process was evaluated for pathogenic Candida spp.
by means of the determination of the minimum inhibitory concentration
(MIC), minimum fungicidal concentration (MFC), and the time-dependency
of yeasts growth inhibition. Simultaneously the cytotoxicity of the
silver NPs to human fibroblasts was determined. The silver NPs exhibited
inhibitory effect against the tested yeasts at the concentration as low
as 0.21 mg/L of Ag. The inhibitory effect of silver NPs was enhanced
through their stabilization and the lowest MIC equal to 0.05 mg/L was
determined for silver NPs stabilized by sodium dodecyl sulfate against
Candida albicans II. The obtained MICs of the silver NPs and especially
of the stabilized silver NPs were comparable and in some cases even
better than MICs of the conventional antifungal agents determined by
E-test. The silver NPs effectively inhibited the growth of the tested
yeasts at the concentrations below their cytotoxic limit against the
tested human fibroblasts determined at a concentration equal to 30 mg/L
of Ag. In contrast, ionic silver inhibited the growth of the tested
yeasts at the concentrations comparable to the cytotoxic level (approx.
1 mg/L) of ionic silver against the tested human fibroblasts. (C) 2009
Elsevier Ltd. All rights reserved.,
DOI = 10.1016/j.biomaterials.2009.07.065,
ISSN = 0142-9612,
Unique-ID = ISI:000270767300020,
L. Kvitek, M. Vanickova, A. Panacek, J. Soukupova, M. Dittrich, E. Valentova, R. Prucek, M. Bancirova, D. Milde, and R. Zboril, „Initial Study on the Toxicity of Silver Nanoparticles (NPs) against
Paramecium caudatum,“ JOURNAL OF PHYSICAL CHEMISTRY C, vol. 113, iss. 11, pp. 4296-4300, 2009.
[Bibtex]
@article ISI:000264111300013,
Author = Kvitek, Libor and Vanickova, Marketa and Panacek, Ales and Soukupova,
Jana and Dittrich, Milan and Valentova, Eva and Prucek, Robert and
Bancirova, Martina and Milde, David and Zboril, Radek,
Title = Initial Study on the Toxicity of Silver Nanoparticles (NPs) against
Paramecium caudatum,
Journal = JOURNAL OF PHYSICAL CHEMISTRY C,
Year = 2009,
Volume = 113,
Number = 11,
Pages = 4296-4300,
Month = MAR 19,
Abstract = In this initial study, the toxicity effect of silver NPs against a model
unicellular eukaryotic organism of Paramecium caudatum was studied. For
the purpose of this study, a dialysis-based method was adapted, which
allowed the preparation of stable aqueous dispersions of silver NPs in
various silver concentrations that were necessary for the evaluation of
toxicity limits of these particles. The obtained results demonstrate
that the silver NPs do not exhibit any toxicity action against the
tested unicellular eukaryotic organism below the concentration of 25 mg
. L(-1) whereas ionic silver retains its toxicity even at a
concentration of 0.4 mg . L(-1). Such a considerable difference in the
toxicity effect of these two forms of silver has not been observed in
the previously published study concerning bacteria (Panacek, A.; Kvitek,
L.; Prucek, R.; Koldr, M.; Vecefova, R.; Pizurova, N.; Sharma, V. K.;
Nevecna, T.; Zboril, R. J. Phys. Chem. B 2006, 110, 16248-16253).
Additionally, it was proven that the surfactant/polymer modification can
increase the toxicity of the silver NPs against the tested organism.,
DOI = 10.1021/jp808645e,
ISSN = 1932-7447,
Unique-ID = ISI:000264111300013,
R. Prucek, L. Kvitek, A. Panacek, L. Vancurova, J. Soukupova, D. Jancik, and R. Zboril, „Polyacrylate-assisted synthesis of stable copper nanoparticles and
copper(I) oxide nanocubes with high catalytic efficiency,“ JOURNAL OF MATERIALS CHEMISTRY, vol. 19, iss. 44, pp. 8463-8469, 2009.
[Bibtex]
@article ISI:000271744600027,
Author = Prucek, Robert and Kvitek, Libor and Panacek, Ales and Vancurova, Lenka
and Soukupova, Jana and Jancik, Dalibor and Zboril, Radek,
Title = Polyacrylate-assisted synthesis of stable copper nanoparticles and
copper(I) oxide nanocubes with high catalytic efficiency,
Journal = JOURNAL OF MATERIALS CHEMISTRY,
Year = 2009,
Volume = 19,
Number = 44,
Pages = 8463-8469,
Abstract = The synthesis of Cu nanoparticles (NPs) via the reduction of Cu ions
with sodium borohydride in the presence of sodium polyacrylate is
presented. The final Cu nanocrystals having a 14 nm diameter were
generated via the aggregation and coalescence of the primarily formed
ultrasmall particles (approx. 3 nm). Addition of sodium sulfite to the
dispersions provided the protection of the Cu NPs against oxidation. On
the other hand, the controlled aeration of the Cu NPs resulted in their
transformation to Cu(2)O nanocubes with an average size of 18 nm. Both
Cu NPs and Cu(2)O nanocubes can effectively catalyze reduction of
4-nitrophenol by sodium borohydride in aqueous solution.,
DOI = 10.1039/b913561h,
ISSN = 0959-9428,
Unique-ID = ISI:000271744600027,
2008
J. Soukupova, L. Kvitek, A. Panacek, T. Nevecna, and R. Zboril, „Comprehensive study on surfactant role on silver nanoparticles (NPs)
prepared via modified Tollens process,“ MATERIALS CHEMISTRY AND PHYSICS, vol. 111, iss. 1, pp. 77-81, 2008.
[Bibtex]
@article ISI:000257450300017,
Author = Soukupova, Jana and Kvitek, Libor and Panacek, Ales and Nevecna,
Tat'jana and Zboril, Radek,
Title = Comprehensive study on surfactant role on silver nanoparticles (NPs)
prepared via modified Tollens process,
Journal = MATERIALS CHEMISTRY AND PHYSICS,
Year = 2008,
Volume = 111,
Number = 1,
Pages = 77-81,
Month = SEP 15,
Abstract = Surfactants represent not only commonly used wetting agents but also
substances that can be used as growth modifiers in the process of solid
nanoparticle (NP) preparation. In this study we report influential
character of different types of surfactants - i.e. ionic (SDS, CTAC) and
non-ionic (Tween 80) - on fundamental characteristics of silver NPs,
which were prepared by a modified Tollens process. The influential
character of surfactants was evaluated throughout a reasonable
improvement of the polyclispersity (in the case of the tested non-ionic
surfactants from 8.5\% even down to 2.5\%) and in the case of ionic
surfactant, SDS and CTAC, also significant change of zeta potential
(from -20 to -50 mV for the highest tested concentration of SDS). A
slight influence of the tested surfactants was observed on the sizes of
the prepared silver NPs. Therefore the obtained results from the
performed surfactant-assisted syntheses revealed a possibility how to
tailor silver NPs by means of their polydispersity and zeta potential
according to the application demands. (c) 2008 Elsevier B.V. All rights
reserved.,
DOI = 10.1016/j.matchemphys.2008.03.018,
ISSN = 0254-0584,
Unique-ID = ISI:000257450300017,
L. Kvitek, A. Panacek, J. Soukupova, M. Kolar, R. Vecerova, R. Prucek, M. Holecova, and R. Zboril, „Effect of surfactants and polymers on stability and antibacterial
activity of silver nanoparticles (NPs),“ JOURNAL OF PHYSICAL CHEMISTRY C, vol. 112, iss. 15, pp. 5825-5834, 2008.
[Bibtex]
@article ISI:000254883100021,
Author = Kvitek, Libor and Panacek, Ales and Soukupova, Jana and Kolar, Milan and
Vecerova, Renata and Prucek, Robert and Holecova, Mirka and Zboril,
Radek,
Title = Effect of surfactants and polymers on stability and antibacterial
activity of silver nanoparticles (NPs),
Journal = JOURNAL OF PHYSICAL CHEMISTRY C,
Year = 2008,
Volume = 112,
Number = 15,
Pages = 5825-5834,
Month = APR 17,
Abstract = In this first systematic study, we describe the influence of various
surfactants and polymers on aggregation stability and antibacterial
activity of silver nanoparticles (NPs) prepared by a modified Tollens
process. The surfactant/polymer stabilizing effect was monitored using
the newly established method based on a titration of the aqueous
dispersion of the silver NPs by aqueous solution of
poly(diallyldimethylammonium) chloride (PDDA). The aggregation process
was evaluated by the dynamic light scattering (DLS) and UV/vis spectra
measurements and finally confirmed by TEM. Among all of the investigated
modifiers, two surfactants (sodium dodecyl sulfate-SDS and
polyoxyethylenesorbitane monooleate-Tween 80) and one polymer
(polyvinylpyr-rolidone-PVP 360) exhibit superior stabilization of the
silver NP dispersions against the process of aggregation. The
differences in the stabilization ability of various tested substances
are discussed with respect to their structure and possible mechanism of
the surface interaction with the NPs. The antibacterial activity of the
modified silver NPs was significantly enhanced especially when modified
by SDS where the minimum inhibition concentration (MIC) decreased under
the ``magical value'' of 1 mu g(.)mL(-1). A correlation was found
between the aggregation stability and enhanced antibacterial activity in
the system of the silver NPs modified by SDS, Tween 80, and high
molecular polymer PVP 360.,
DOI = 10.1021/jp711616v,
ISSN = 1932-7447,
Unique-ID = ISI:000254883100021,
2006
A. Panacek, L. Kvitek, R. Prucek, M. Kolar, R. Vecerova, N. Pizurova, V. K. Sharma, T. Nevecna, and R. Zboril, „Silver colloid nanoparticles: Synthesis, characterization, and their
antibacterial activity,“ JOURNAL OF PHYSICAL CHEMISTRY B, vol. 110, iss. 33, pp. 16248-16253, 2006.
[Bibtex]
@article ISI:000239818000019,
Author = Panacek, Ales and Kvitek, Libor and Prucek, Robert and Kolar, Milan and
Vecerova, Renata and Pizurova, Nadezda and Sharma, Virender K. and
Nevecna, Tat'jana and Zboril, Radek,
Title = Silver colloid nanoparticles: Synthesis, characterization, and their
antibacterial activity,
Journal = JOURNAL OF PHYSICAL CHEMISTRY B,
Year = 2006,
Volume = 110,
Number = 33,
Pages = 16248-16253,
Month = AUG 24,
Abstract = A one-step simple synthesis of silver colloid nanoparticles with
controllable sizes is presented. In this synthesis, reduction of
[Ag(NH3)(2)](+) complex cation by four saccharides was performed. Four
saccharides were used: two monosaccharides (glucose and galactose) and
two disaccharides (maltose and lactose). The syntheses performed at
various ammonia concentrations (0.005-0.20 mol L-1) and pH conditions
(11.5-13.0) produced a wide range of particle sizes (25-450 nm) with
narrow size distributions, especially at the lowest ammonia
concentrations. The average size, size distribution, morphology, and
structure of particles were determined by dynamic light scattering
(DLS), transmission electron microscopy (TEM), and UV/Visible absorption
spectrophotometry. The influence of the saccharide structure
(monosacharides versus disaccharides) on the size of silver particles is
briefly discussed. The reduction of [Ag(NH3)(2)](+) by maltose
produced silver particles with a narrow size distribution with an
average size of 25 nm, which showed high antimicrobial and bactericidal
activity against Gram-positive and Gram-negative bacteria, including
highly multiresistant strains such as methicillin-resistant
Staphylococcus aureus. Antibacterial activity of silver nanoparticles
was found to be dependent on the size of silver particles. A very low
concentration of silver (as low as 1.69 mu g/mL Ag) gave antibacterial
performance.,
DOI = 10.1021/jp063826h,
ISSN = 1520-6106,
Unique-ID = ISI:000239818000019,
2005
[Bibtex]
@article ISI:000231377100009,
Author = Panacek, A and Kvitek, L,
Title = Colloid chemistry in laboratory practice,
Journal = CHEMICKE LISTY,
Year = 2005,
Volume = 99,
Number = 8,
Pages = 606-609,
Abstract = The aim of the article is to supply a current missing field of chemistry
in grammar schools by project of simple practical problems from coloid
chemistry. It contains teoretical part and practical problems focusing
on physical and chemical properties of colloid chemistry.,
ISSN = 0009-2770,
Unique-ID = ISI:000231377100009,
L. Kvitek, R. Prucek, A. Panacek, R. Novotny, J. Hrbac, and R. Zboril, „The influence of complexing agent concentration on particle size in the
process of SERS active silver colloid synthesis,“ JOURNAL OF MATERIALS CHEMISTRY, vol. 15, iss. 10, pp. 1099-1105, 2005.
[Bibtex]
@article ISI:000227320600013,
Author = Kvitek, L and Prucek, R and Panacek, A and Novotny, R and Hrbac, J and
Zboril, R,
Title = The influence of complexing agent concentration on particle size in the
process of SERS active silver colloid synthesis,
Journal = JOURNAL OF MATERIALS CHEMISTRY,
Year = 2005,
Volume = 15,
Number = 10,
Pages = 1099-1105,
Abstract = A one-step chemical reduction route towards silver colloid particles
with controllable sizes ranging from 45 to 380 nm is reported in this
article. Silver particles, prepared by the reduction of
[Ag(NH3)(2)](+) complex with various reducing sugars, were
characterised by means of transmission electron microscopy ( TEM),
dynamic light scattering ( DLS) measurement of particle size
distribution, and UV-VIS spectroscopy. The concentration of ammonia in
the reaction mixture and the choice of the reducing sugar are the key
parameters in the control of particle size. Synthesised silver colloid
particles were successfully tested for use in surface-enhanced Raman
spectroscopy (SERS) with 1-methyladenine as a testing substance.,
DOI = 10.1039/b417007e,
ISSN = 0959-9428,
Unique-ID = ISI:000227320600013,
2004
[Bibtex]
@article ISI:000188806900008,
Author = Panacek, A and Kvitek, L and Kleckova, M,
Title = Colloid chemistry in practical problems,
Journal = CHEMICKE LISTY,
Year = 2004,
Volume = 98,
Number = 1,
Pages = 39-41,
Abstract = The aim of the article is giving an idea to secondary school
schoolchildren of a neglected field of chemistry. It contains basic
theoretical concepts from colloid chemistry and in particular
instructions for practical problems of colloid chemistry. The problems
are not time-, material- or tabour-consuming; they are focused on
preparation of colloidal systems of inorganic materials and observation
of their properties such as stability, stabilization and the Tyndall
effect.,
ISSN = 0009-2770,
Unique-ID = ISI:000188806900008,
